Synthetic Route of 583-39-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. 583-39-1, name is 2-Mercaptobenzimidazole belongs to imidazoles-derivatives compound, it is a common compound, a new synthetic route is introduced below.
A solution of 2-mercaptobenzimidazole (0.15 g, 1.0 mmol) in methanol(10 mL) was added to a solution of BiI3 (0,294 g, 0.5 mmol) inacetonitrile (10 mL). The resulting solution was stirred for 3 h at 50 C.The solution obtained was filtered and slowly evaporated until the redcrystals were isolated. Yield: % 79.5; mp, 234-238 C; mw, 1780, 19 g/mol. Elemental Anal. Calc. for C28H24Bi2I6N8S4: C, 18.89; H, 1.36; N,6.29; S, 7.20. Found: C, 18.92; H, 1.38; N, 6.32; S, 7.29. UV-Vis(DMSO): lambdamax (logepsilon): 312.50 (5.28), 257.00 (4.90). IR (cm-1): 3198 m,2361m, 1620m, 1491s, 1450s, 1396m, 1344m, 1252w, 1165m, 1149w,1009m, 974m, 926w, 810w, 742s, 671m, 596s, 567w, 410m. 13C NMR[400 MHz, DMSO-d6, delta(ppm)]: 168.71 (C]S), 133.17 (C4, C5), 123.34(C7, C8), 110.49 (C6, C9). Soluble in methanol, acetonitrile, acetone,tetrahydrofuran, dimethylsulfoxide. LambdaM=45.2 Omega-1·cm2·mol-1.
In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 2-Mercaptobenzimidazole, other downstream synthetic routes, hurry up and to see.
Reference:
Article; Ozturk; Banti; Hadjikakou; Panagiotou; Tasiopoulos; Inorganica Chimica Acta; vol. 497; (2019);,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem