Synthetic Route of 144689-94-1, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 144689-94-1, Name is Diethyl 2-propyl-1H-imidazole-4,5-dicarboxylate, SMILES is O=C(C1=C(C(OCC)=O)NC(CCC)=N1)OCC, belongs to imidazoles-derivatives compound. In a article, author is Sharma, AK, introduce new discover of the category.
Synthesis of functionalised cyclic nitrones via regioselective and unusual [3+2] cycloadditions of alpha-nitrosostyrenes with 1,3-diazabuta-1,3-dienes and imines
The alpha-nitrosostyrenes 2, generated in situ from a-halogeno oximes, undergo regioselective [3 + 2] cycloaddition with 1,3-diazabuta-1,3-dienes 1 and 5 leading to the cyclic nitrones 3 and 6, respectively, Similarly, the cyclic nitrones 12 are also formed in reactions of 2 with the trisubstituted amidines 11, Thermolysis of the nitrones 3 and 12d-f gives imidazole derivatives 13, The nitrones 6, on the other hand, on thermolysis under similar conditions, give the amidine derivatives 17, Interestingly, the treatment of both 3 and 6 with NaBH4 in methanol and the reactions of 2 with N-arylbenzamidines also yield the imidazole derivatives 13.
Synthetic Route of 144689-94-1, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 144689-94-1 is helpful to your research.