Related Products of 23996-25-0, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 23996-25-0, Name is 2-Ethyl-4-methyl-1H-imidazole-1-propanenitrile, SMILES is CCC1=NC(C)=CN1CCC#N, belongs to imidazoles-derivatives compound. In a article, author is Adiyala, Praveen Reddy, introduce new discover of the category.
Continuous-flow photo-induced decarboxylative annulative access to fused imidazole derivatives via a microreactor containing immobilized ruthenium
Visible-light-driven continuous-flow decarboxylative annulation was achieved and used along with a microreactor containing immobilized ruthenium catalyst to construct valuable fused imidazole derivatives with high yields under an open atmosphere. Notably, this chemistry included the use of l-proline and alpha-azidochalcone as precursors of an alpha-amino radical and 2H-azirine via photo-induced decarboxylation and denitrogenation, respectively, to give the annulated imidazole derivatives as a result of the formation of two new C-N bonds. Moreover the novel, environmentally benign and efficient continuous-flow protocol was further improved by carrying out the reaction in a polydimethylsiloxane (PDMS) microreactor with immobilized Ru3+ under fluorescent or white LED light, enabling excellent yields (70-94%) at a reaction time (2 min) significantly shorter than that (16 h) of the batch protocol.
Related Products of 23996-25-0, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 23996-25-0.